3-Methyl-2-butanol has five signals in its 13C NMR spectrum at Research Paper Help

3-Methyl-2-butanol has five signals in its 13C NMR spectrum at 17.90, 18.15, 20.00, 35.05, and 72.75 d. Why are the two methyl groups attached to C3 nonequivalent? Making a molecular model should be helpful.

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